Temperature-Dependent Electrochemical Performance of Ta-Substituted SrCoO3 Perovskite for Supercapacitors
Chemistry - A European Journal, cilt.30, sa.14, 2024 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 30 Sayı: 14
- Basım Tarihi: 2024
- Doi Numarası: 10.1002/chem.202303267
- Dergi Adı: Chemistry - A European Journal
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Anahtar Kelimeler: Electrochemical performance, Perovskite, SrCoO3-delta, Supercapacitor, Temperature-dependent
- Boğaziçi Üniversitesi Adresli: Hayır
Özet
Developing new electrode materials with good temperature-dependent electrochemical performance has become a great issue for the deployment of hybrid supercapacitors with wide temperature tolerance. In this work, a series of Ta-substituted SrCo1-xTaxO3-δ (x=0.05, 0.10, 0.15, 0.20) perovskites have been studied as positive electrodes for hybrid supercapacitors in terms of their structures, elemental valence states and electrochemical performances. Incorporating Ta into SrCoO3-δ perovskite not only stabilizes the crystallite structure but also notably improves electrochemical activities. The SrCo0.95Ta0.05O3-δ@CC delivers the highest specific capacity (Qsp) of 227.91 C g−1 at 1 A g−1, which is attributed to the highest oxygen vacancy content and the fastest oxygen diffusion kinetics. The hybrid supercapacitor SrCo0.95Ta0.05O3-δ@CC//AC@CC exhibits a high energy density of 22.82 Wh kg−1@775.09 W kg−1 and a stable long-term cycle life (5000 cycles) with 90.7 % capacity retention. As temperature increases from 25 to 85 °C, the capacitance properties are improved at elevated temperatures for both electrode and device due to the increased electrolyte conductivity. The outstanding electrochemical results present that SrCo1-xTaxO3-δ perovskite holds good prospects for hybrid supercapacitors with wide temperature tolerance.