The molecular dynamics of poly(1,4-trans-butadiene) in the amorphous state and in an inclusion complex
Macromolecular Symposia, cilt.101, ss.435-442, 1996 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 101
- Basım Tarihi: 1996
- Doi Numarası: 10.1002/masy.19961010149
- Dergi Adı: Macromolecular Symposia
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.435-442
- Boğaziçi Üniversitesi Adresli: Evet
Özet
The molecular dynamics of poly(1,4-trans-butadiene) in the amorphous state at bulk density and in its inclusion complex with perhydrotriphenylene are compared here. The internal motions differ in the two systems, due to the occupation of gauche states at CH2-CH2 of the amorphous polymer, but the exclusion of gauche states at these bonds in the inclusion complex. This difference in conformational preferences at CH2-CH2 has consequences for the decay rates for the orientation autocorrelation functions.