Beyond Conventional Activating Methods, a Green Approach for the Synthesis of Biocarbon and Its Supercapacitor Electrode Performance
Energy and Fuels, cilt.34, sa.6, ss.7658-7665, 2020 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 34 Sayı: 6
- Basım Tarihi: 2020
- Doi Numarası: 10.1021/acs.energyfuels.0c01103
- Dergi Adı: Energy and Fuels
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, PASCAL, Applied Science & Technology Source, Chemical Abstracts Core, Chimica, Compendex, Computer & Applied Sciences, Environment Index, Pollution Abstracts, DIALNET
- Sayfa Sayıları: ss.7658-7665
- Boğaziçi Üniversitesi Adresli: Hayır
Özet
The development of cost-effective and renewable carbon electrodes by using a green production approach is of significant importance for supercapacitors (SCs). Herein, we present an effective synthetic method that utilizes pistachio shells and Na2S2O3 as a carbon precursor and activating agent, respectively, to prepare porous carbon by hydrothermal carbonization and subsequent chemical activating processes. The NCNaK-1 (optimum sample, N/S doped carbon prepared by Na2S2O3 and KCl at 800 °C) exhibits sponge-like morphology, a relatively high specific surface area of 775 m2 g-1 along with interconnected hierarchical porosity, and high nitrogen/sulfur doping into the carbon framework. The specific capacity of the NCNaK-1 electrode is as high as 166 F g-1 at a current density of 0.5 A g-1 in 1 M KOH electrolyte and ∼96% capacitance retention over 5000 cycles. Moreover, a SC assembled with NCNaK-1 electrodes has an energy density of 2.7 W h kg-1 at a power density of 250 W kg-1. This research introduces a sustainable, environmentally benign, economic, high production yield, and efficient porous carbon production strategy.