Power-law type rate expression for WGS reaction over Au-Re/CeO2 catalyst under realistic fuel processor conditions


Gökaliler F., ÖNSAN Z. İ., AKSOYLU A. E.

Catalysis Communications, cilt.39, ss.70-73, 2013 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1016/j.catcom.2013.04.013
  • Dergi Adı: Catalysis Communications
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.70-73
  • Anahtar Kelimeler: Au-Re/CeO2, Gold catalysts, Hydrogen production, Hydrogen purification, Water-gas shift kinetics
  • Boğaziçi Üniversitesi Adresli: Evet

Özet

The kinetic behavior of 1Au-0.5Re/CeO2 catalyst was investigated at 280-325 C as a function of temperature and partial pressures of reactants and products of the forward WGS reaction under realistic feed conditions. Parameters estimated by non-linear regression analysis were found to predict the overall CO conversion rate within a 10% error margin. © 2013 Elsevier B.V.