Regioselectivity in the ring opening of non-activated aziridines
Chemical Society Reviews, cilt.41, sa.2, ss.643-665, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 41 Sayı: 2
- Basım Tarihi: 2012
- Doi Numarası: 10.1039/c1cs15140a
- Dergi Adı: Chemical Society Reviews
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.643-665
- Boğaziçi Üniversitesi Adresli: Evet
Özet
In this critical review, the ring opening of non-activated 2-substituted aziridines via intermediate aziridinium salts will be dealt with. Emphasis will be put on the relationship between the observed regioselectivity and inherent structural features such as the nature of the C2 aziridine substituent and the nature of the electrophile and the nucleophile. This overview should allow chemists to gain insight into the factors governing the regioselectivity in aziridinium ring openings (81 references). 2012 © The Royal Society of Chemistry.